Biodiesel
The biodiesel , biogazole or B100 (B20, B5, B2, etc) is a Biocarburant obtained starting from Huile vegetable or animal, processed by a chemical process called Transestérification making react this oil with a alcohol (Méthanol or ethanol), in order to obtain EMHV or EEHV (according to alcohol used). The biodiesel tries to compete with the plant oils used in a rough state and the pétrodiesel, i.e. the traditional diesel. The biodiesel can be used only in the engines or mixed with pétrodiesel.
Manufacture
See also: Plant oil carburizing
One makes react oil with alcohol to decrease his Viscosité. In theory all oils can be used, but, in France the producers often choose oil of Colza, while with the the United States, the manufacturers prefer the Soja and to a lesser extent the Canola (variety of Colza of spring with low acid content érucique). The United States is in addition the largest producers of soya in front of Brazil. But it is perhaps starting from Algue S that oils could be produced with the best output, making thus possible a production of biodiesel with large scales within 5-8 years. Alcohol is most of the time Méthanol.
To increase the reaction speed, it is necessary to heat the liquid towards 50 °C and to add a base like Catalyseur. The base can be, for example, of the Hydroxyde of sodium, also called caustic soda (NaOH). For a better total energetic efficiency one can also choose to simply let react without heating, the reaction taking a few hours then.
The process (Transestérification) makes it possible to recover Glycérine, which is a source of added-value. One needs 100 kg of Méthanol to cross esterify a ton of plant oil (ester of fatty-acids and glycerol) of colza in the presence of an alkaline catalyst. One then obtains a ton of diester (ester of fatty-acids and methanol) and 100 kg of glycerin reusable in chemical industry or food. In the economic balance it is necessary to count the Tourteaux colza, by-product of the extraction of the oil which constitutes an important source of Protéine S vegetable in animal feeds.
Performances compared with the other fuels
Compared to the biodiesel, plant oils have a more important viscosity (up to 10 times more), a weaker Indice of cetane, and a temperature of higher solidification.The pétrodiesel has a better viscosity (until twice less) and is less corrosive than the biodiesel. The pure biodiesel degrades the natural rubber and for this reason, it is advisable to check the quality of the joints if one wants to use pure biodiesel.
In mixture up to 30% with the pétrogazole, the diester French does not present any problem.
Environmental impact
The principal interest asserted by the biodiesel is not to be a fossil energy and to provide a renewable energy (the raw Plant oil) very little contributing to the increase in the rate of CO2 present in the atmosphere.Indeed, in theory, the plant (Colza generally, but the process is applicable to all oils), during its growth, consumes by Photosynthèse the same quantity of carbon dioxide that the combustion of the fuel will release. However, for controlling well the ecological value of a fuel, it is necessary to take into account its écobilan, and thus all its manufacturing process, including the culture and its inputs, the ecological Empreinte and the Energy efficiency of the processes of transformation and transport of the producer to the ultimate consumer and to make the total energy assessment. The biodiesel requires an energy contribution to accelerate the process of esterification and must be treated in refineries specialized before being delivered to the consumers, which weighs down its Energy efficiency considerably in particular vis-a-vis the Plant oil carburizing. The biodiesel alone is not-powerful bus it has only 40 point on the octane level.
Some underline risk which were not initially taken into account: one would not have that the production of biocarburants is done at the price of a massive deforestation as in Brazil, which, contrary to the sought effect, would increase the gas emissions with greenhouse effect. Moreover, cultivated spaces deprive the countries of grounds for food agriculture, while raising the prices of cereals or food corn.
The market of the biodiesel
The largest producers of biodiesel are the the United States, the Germany and the France. The department of the energy of the government of the United States published several documents on the biodiesel. The United States supports also research in this field via the National Renewable Energy Laboratory. In Belgium, biodiesel is produced with Ertvelde (by Oléon) and with Feluy (by Biofuel.be).
The production is relatively weak (lower than the million tons in France in 2004) compared to the consumption of diesel.
Le biodiesel thus remains used marginally, mixes some by the fuel merchants, the more so as it belongs to the gazoles suitable for solidify at too low temperature.
The B20/B-20 or BD20 is a containing hydrocarbon diesel containing 20% of biodiesel and 80% of Gazole, B40 contains 40%, etc
In 2007 the Brazil and Argentina (where Colza GMO strongly developed) aim at the European market. Three production units were inaugurated the eight first month of the year in Argentina, whose factory of the oil mill Cincentin (24 000 tonnes/an) and 5 others are in the course of construction. Argentina could thus pass from mid 200.000t/an 2007 to 1 million t/an in 2008.
The negative and positive effects of the biodiesel (real or supposed) are numerous:
- the die biodiesel competition and embarrassment the oil industry, which thus seeks to control it;
- biodiesel remains industrial product, whereas the raw plant oils could, after filtering thorough (1 µm with 5 µm) and neutralization (they are acid what is not very compatible with the oil of draining which is alkaline), being directly injected into a diesel engine (often not very sensitive to the fuel used, but not in all the cars diesel nor under any conditions);
- in certain countries the biodiesel is manufactured starting from goods with food vocation. In France, the profitability of the die rests on the production of Colza on pieces called in “industrial fallow” at a low price to the market price of the food Colza. The rate of fallow imposed by the European agricultural policy fell of 15% in the years 1990 to 5% in 2004 for finally being removed in 2007, weakening all the balance of the die; Dieser industry announced in August 2007 in France that it was going to propose multiannual contracts to increase its purchase price of 20 euros/t for fidéliser the farmers who are likely to plant cultures more profitable than agrocarburants.
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the biodiesel is more expensive than the Gazole, it thus needs a “tax incentive”, in the form of an important desfiscalisation (80% of exemption of TIPP). The desfiscalisation of the “ecological” fuels is a source of controversies, though partly fixed by the European directive 2003/96/CE as regards the European countries;
- the industrial production of Colza is often described as “productivist”;
- some put forward the technical differences with the Gazole. However, this type of criticism appears founded neither with the use nor being studied.
The French Diester
In France, one also speaks about Diester ® . The diester , Portemanteau word formed by the diesel contraction of and Ester , is a registered trademark by Sofiproteol.It is also a term become common to indicate in France, the methyl esters of plant oils (EMHV), the biodiesel in Europe and North America.
France produces each year approximately 300.000 tons of diester, that is to say hardly 1% of the consumed fuel.
In France, this fuel is mixed with the traditional diesel with small percentage without specific indication.
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