See also: Beryl (homonymy)
The beryl , or béril, is a Minéral composed of Silicate of Béryllium and Aluminum, of formula Be3Al2Si6O18. Its name comes from the Greek bêrullos , crystal.
Structure
The structure of beryl is made up of Si6O18 rings which have a plan of Symétrie perpendicular to the main axis, passing by the Atome S of Silicium. These rings form columns parallel with the main axis and are connected between them by rings of four tetrahedrons centered on the Béryllium. Aluminum occupies finally of the octahedral sites. The topology of beryl is thus that of a Tectosilicate (classification of Zoltai) and only the chemical distinction between tetrahedrons centered on the Silicium and those centered on the Béryllium makes it possible to classify this Minéral among the Cyclosilicate S (classification of Machatski-Bragg).
Chemical classification
In alkaline beryls the
Lithium can replace the
Aluminum in octahedral position, and aluminum can partly replace the Béryllium in tetrahedral position. The electric balance of the structure is carried out by introduction of ions
Sodium or Césium into the channels of the structure.
On the basis of alkali contents the beryls are classified in:
- beryl without alkalis: total alkalis lower than 1%;
- poor of alkalis, potassic or sodico-potassic beryl: the Potassium prevails, its content lying between 0,5 and 1%;
- sodic beryl: the Sodium prevails, its content lying between 0,5 and 1%;
- beryl sodico-litifère: Sodium between 0 and 2%, Lithium lower than 6%;
- beryl cesio-litifère: high content of Sodium and Lithium, Cesium higher than 5%.
It is possible that Eau of zeolithic nature is also in the channels, and also of gases like CO2, Ar and.
Properties
The beryl is the primary source of Béryllium. The hydrothermal synthesis of beryls starting from a mixture of
Silica,
Alumina and
Carbonate of Béryllium can be carried out between 400°C and 850º under pressures from 400 to 2000 bars.
The beryl is easily recognized by its hexagonal morphology and its prismatic faces. In fact, the morphology of beryl consists of prisms {} and {}, finished by the pinacoidal {0001}, and of very many bipyramides {} and {}. The crystals are lengthened along axis Z.
Varieties
The transparent varieties are used like invaluable stones in Joaillerie and are:
- the Aquamarine, blue and green-blue;
- the emerald, green because of the presence of Chromium;
- the héliodore, gilded or yellow because of the presence of Iron;
- the Morganite, pink with orange, container Lithium and Cesium;
- the Goshénite, colorless;
- the Bixbite, red.
Paragenesis
The beryl, like the
Tourmaline, is a Minéral granitic
Pegmatite S. Of variable size, sometimes very large, it is formed at the end of the crystallization of the granitic solid masses, when the magma remaining grew rich in Eau and rare elements compared to the magma by departure. The elements minéralisateurs (
Fluorine,
Boron) support the development of large crystals. In such pegmatites, the beryl can be associated with the
topaz, the
Tourmaline, the
Muscovite and the Lépidolite, with large crystals of Feldspath S and quartz, with the Spodumène and many oxides of Titane, tantalum etc (Rutile, Columbite etc).
The beryl can also appear in some Syénite S nephelinic, syenites and Marbre S. the emerald variety has a metamorphic paragenesis (Schiste with Biotite).
Layers
The ordinary beryl is the principal beryllium ore.
The New England (Australia) has many layers; the North Carolina (the United States) is also an ordinary source of beryl.
In France, the beryl was announced to Villeder (Morbihan), towards Alençon (Orne), in the Loire-Atlantique (Orvault), close to Bagnères-with-Luchon (Haute-Garonne), around Bessines (High-Vienna) and of Autun (Saône-et-Loire).
Deterioration
The beryl deteriorates with difficulty in
Kaolinite, in Bertrandite Be
4 (OH)
2, in Phénacite, the amphiboloïde épidydimite Na (OHBeSi
3O
7), in cyclosilicate Milarite K
2Ca
4Al
2Be
4Si
24O
60·(H
2O).
Symbolic system
The Noces of beryl symbolize the 23 years of Mariage in the French folklore.
See too